Bk. Atomic number 97. Group 3 actinide element with electronic configuration [Rn]5f 9 7s 2. The fifth transuranium element discovered. Named after the University of California, Berkeley, where it was synthesized. It was obtained in December 1949 by G. T. Seaborg, A. Ghiorso, and others, by bombardment of mg amounts of 241 Am with 4 He nuclei (alpha particles) accelerated in the 60 in cyclotron at the University of California, Berkeley. 249 Bk is obtained by neutron absorption (in a nuclear reactor) of 248 Cm. Silvery-white metal. Melting point 1259.2 °C. First ionization energy 608 kJ mol -1 (6.30 eV). Usual oxidation states 2-4. More than μg amounts of BkCl 3 , BkOCl, BkO 2 , and BkO 3 have been produced. Currently, there are 17 known isotope nuclides in the range of 235 to 254. The alpha-decay nuclide with mass number 247 is the longest-lived, with a half-life of 1380 y. [CAS 7440-40-6] Source: Morikita Publishing "Chemical Dictionary (2nd Edition)" Information about the Chemical Dictionary 2nd Edition |
Bk.原子番号97の元素.電子配置[Rn]5f 97s2の周期表3族アクチノイド元素.5番目に発見された超ウラン元素.この元素が合成されたカリフォルニア大学バークレー校にちなんで命名された.1949年12月,G.T. Seaborg(シーボーグ),A. Ghiorsoらによって,カリフォルニア大学バークレー校の60 inサイクロトロンで加速した 4He 原子核(α粒子)による mg 量の 241Am の衝撃で得られた.249Bk は 248Cm の中性子吸収(原子炉中)によって得られる.銀白色の金属.融点1259.2 ℃.第一イオン化エネルギー608 kJ mol-1(6.30 eV).通常の酸化数2~4.μg 量以上のBkCl3,BkOCl,BkO2,BkO3などがつくられた.現在,知られている同位体核種は,235~254の範囲に17種.質量数247のα崩壊核種がもっとも長寿命で半減期1380 y.[CAS 7440-40-6] 出典 森北出版「化学辞典(第2版)」化学辞典 第2版について 情報 |
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