In the energy balance based on the first law of thermodynamics, when the changes in kinetic energy and potential energy can be ignored compared to the change in internal energy, U1 + q = U2 + Aw Here, U1 and U2 are the internal energies of the system in states 1 and 2, q is the thermal energy given to the system, A is the heat equivalent of work, and w is the work done by the system to the outside. When there is no external work, the above balance equation is simplified as follows. Heat input + internal heat generation (due to reaction, etc.) = Heat output + Heat stored in the system This case is specifically called heat balance. Source: Morikita Publishing "Chemical Dictionary (2nd Edition)" Information about the Chemical Dictionary 2nd Edition |
熱力学第一法則にもとづいたエネルギーの収支で,運動エネルギーと位置エネルギーの変化が,内部エネルギーの変化に対して無視できるときは, U1 + q = U2 + Aw で表される.ここで,U1,U2 は状態1および2のときの系の有する内部エネルギー,qは系に与えられる熱エネルギー,Aは仕事の熱当量,wは系が外部になす仕事である.外部仕事のない場合,上の収支式は次のように簡易化される. 入熱量+内部での発熱量(反応などによる) =出熱量+系に蓄積される熱量 この場合を,とくに熱収支という. 出典 森北出版「化学辞典(第2版)」化学辞典 第2版について 情報 |
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