…Equations (12) to (14) are called the reaction mechanism of reaction (11). Each step of a reaction generally proceeds at a different rate, but in the above example, the reaction rate of the first step (equation (12)) is slow, and the total reaction rate is determined by this step, so it is called the rate determining step of the reaction. If E, F, and G, which are produced during the course of a reaction, can actually be isolated, they are called reaction intermediates. … *Some of the terminology that mentions "rate determining step" is listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
…式(12)~(14)を反応(11)の反応機構という。反応の各段階は一般に異なる速度で進行するが,上の例では第1段階(式(12))の反応速度が遅く,全反応速度はこの段階によって規定されるので,反応の律速段階rate determining stepという。反応の経過に際して生じるE,F,Gが実際に単離可能である場合,これらは反応中間体という。… ※「rate determining step」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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