... In 1962, N. Bartlett of Canada was inspired by the O 2 + PtF 6 - reaction he had obtained while working with PtF 6 , and by comparing the first ionization potentials of O 2 and Xe, he succeeded in obtaining the first compound of Xe, xenon hexafluoroplatinate (XePtF 6) . In the same year, Claassen HHClaassen and his colleagues from the United States succeeded in synthesizing xenon tetrafluoride (XeF 4) by reacting Xe with fluorine. From this point on, compounds of rare gas elements were synthesized one after another, and many compounds have been created to date. ... From [Xenon]…It forms hydrate Xe・5.76H 2 O (melting point 23.5°C, decomposition pressure 1.15 atm at 0.1°C) and Xe・3C 6 H 4 (OH) 2 with hydroquinone, but these are clathrate compounds, in which xenon atoms are trapped in a three-dimensional mesh structure formed by hydrogen bonds between water molecules and hydroquinone molecules, and are not true compounds with valence bonds. The first true compounds were xenon hexafluoroplatinate (XePtF 6) synthesized by N. Bartlett of Canada in 1962, and xenon tetrafluoride (XeF 4) synthesized by Claassen et al. of the United States in the same year. Since then, a considerable number of compounds have been produced, mainly fluorides and oxides. … *Some of the terminology explanations that mention "Claassen, HH" are listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
… 1962年カナダのバートレットN.Bartlettは,PtF6を取り扱っているとき得られたO2+PtF6-にヒントを得て,O2とXeの第一イオン化ポテンシャルの対比から,はじめてXeの化合物ヘキサフルオロ白金酸キセノンXePtF6を得ることに成功した。次いで同年,アメリカのクラーセンH.H.ClaassenらはXeとフッ素との反応から四フッ化キセノンXeF4の合成に成功した。これから希ガス元素の化合物があいついで合成されるようになり,これまでに数多くの化合物がつくられている。… 【キセノン】より…水和物Xe・5.76H2O(融点23.5℃,分解圧0.1℃で1.15気圧)や,ヒドロキノンとの間にXe・3C6H4(OH)2をつくるが,これらはクラスレート化合物であって,水分子やヒドロキノン分子の水素結合によって生ずる三次元網目構造の中にキセノン原子がとりこまれたもので,原子価結合のある真の化合物ではない。真の化合物としては,1962年カナダのバートレットN.Bartlettにより合成されたヘキサフルオロ白金酸キセノンXePtF6と,同年アメリカのクラーセンH.H.Claassenらにより合成された四フッ化キセノンXeF4が初めである。それ以後,フッ化物および酸化物を中心として,かなりの量の化合物がつくられている。… ※「Claassen,H.H.」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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