The oxides of rhenium with the oxidation states IV, V, VI, and VII are known. The oxides of rhenium with the oxidation states I, II, and III have not been obtained as anhydrous compounds. [Rhenium(IV) oxide] Chemical formula: ReO2 . It is obtained by heating a mixture of rhenium and rhenium(VII) oxide in a quartz tube for a long time at over 600°C. It is a dark brown powder. Specific gravity: 11.4 (25°C). When heated to 1000°C in a high vacuum, it becomes rhenium and rhenium(VII) oxide. It is reduced to rhenium by hydrogen at 800°C. Source: Heibonsha World Encyclopedia, 2nd Edition Information |
酸化数IV,V,VI,VIIのレニウムの酸化物が知られている。酸化数I,II,IIIのレニウムの酸化物は無水和物としては得られていない。 [酸化レニウム(IV)] 化学式ReO2。レニウムと酸化レニウム(VII)の混合物を石英管中で600℃以上で長時間加熱すると得られる。暗褐色粉末。比重11.4(25℃)。高真空中で1000℃に加熱するとレニウムと酸化レニウム(VII)とになる。水素により800℃で還元されてレニウムになる。 出典 株式会社平凡社世界大百科事典 第2版について 情報 |
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