…In other words, instead of two types of molecules, donors and acceptors, which are mutually attractive, stacking alternately, donors and acceptors stack together to form columns. This led to the emergence of organic metals. Furthermore, tetrathiafulvalene (TTF) was synthesized, and in 1973 its complex TTF-TCNQ showed metallic electrical conductivity properties, and organic conductors, as organic metals, were actively studied theoretically and experimentally. … *Some of the terminology explanations that mention "metal organics" are listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
…すなわち,相互に引き合う供与体と受容体の2種類の分子が交互に積み重なるのではなく,供与体どうしおよび受容体どうしがそれぞれ積み重なってカラムをつくっている。これが金属有機体organic metalの出現の原因となった。 さらに,テトラチアフルバレン(TTF)が合成され,73年その錯体TTF‐TCNQが金属的電気伝導度特性を示すに至り,有機導体は,金属有機体として,その理論的および実験的研究が活発に行われた。… ※「金属有機体」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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