Pyrophosphoric acid (pyrophosphoric acid)

Japanese: ピロリン酸(ピロ燐酸) - ピロりんさん(英語表記)pyrophosphoric acid
Pyrophosphoric acid (pyrophosphoric acid)
Chemical formula: H 4 P 2 O 7 . Also known as diphosphoric acid. It is a tetrabasic acid formed by dehydration condensation of orthophosphoric acid H 3 PO 4 . It is produced by heating and dehydrating orthophosphoric acid (85%) at about 180°C under reduced pressure, or by adding a calculated amount of diphosphorus pentoxide. 4H 3 PO 4 + P 2 O 5 - → 3H 4 P 2 O 7 Colorless needle-like crystals or glassy mass. The normal solid is type I (melting point 54.3°C), and when heated to about 50°C in a sealed tube, it transforms into type II (melting point 71.5°C).

Source: Heibonsha World Encyclopedia, 2nd Edition Information

Japanese:
化学式H4P2O7。二リン酸diphosphoric acidともいう。オルトリン酸H3PO4が脱水縮合してできる四塩基酸である。オルトリン酸(85%)を減圧下,約180℃で加熱脱水するか,計算量の五酸化二リンを加えてつくる。 4H3PO4+P2O5―→3H4P2O7無色の針状晶またはガラス状の塊。通常の固体はI型(融点54.3℃)で,これを封管中で約50℃に熱するとII型(融点71.5℃)に転移する。

出典 株式会社平凡社世界大百科事典 第2版について 情報

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