A hydrate of tin(IV) oxide, SnO2 . Its general composition is SnO2 x H2O . x is not a constant value, and it exhibits gel-like properties. The white precipitate that forms when a small amount of dilute acid is added to an aqueous solution of a stannate salt is called α-stannic acid. Its structure is unclear. α-stannic acid dissolves in alkali hydroxides and alkali carbonates. It has a high adsorptivity, and is good at adsorbing organic dyes and phosphoric acid. When left in solution or heated, it becomes crystalline and exhibits properties similar to tin(IV) oxide. Source: Heibonsha World Encyclopedia, 2nd Edition Information |
酸化スズ(IV)SnO2の水和物。一般にはSnO2・xH2Oの組成をもつ。xは一定値をとらず,ゲルとしての性質を示す。スズ酸塩水溶液に少量の希酸を加えると生ずる白色の沈殿はα‐スズ酸と呼ばれる。構造などは明らかでない。α‐スズ酸は水酸化アルカリや炭酸アルカリに溶ける。吸着性が大きく,有機色素,リン酸などをよく吸着する。溶液中に放置するか,加熱すると結晶性になり,酸化スズ(IV)に似た性質を示すようになる。
出典 株式会社平凡社世界大百科事典 第2版について 情報 |
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