When X-rays pass through a particle with a size of about 10 to 3000 Å, a diffuse diffraction pattern or sometimes a clear diffraction ring is produced in the range of an extremely small angle (usually less than 1 degree) with respect to the incident X-ray. This phenomenon is called small-angle X-ray scattering, or simply small-angle scattering. Even in ordinary crystals, the Bragg reflection of a substance with a long period appears in this angle range. By examining the diffraction pattern from small-angle scattering, it is possible to measure the very long periodicity of the crystal and to obtain knowledge about the size, shape, and assembly state of the particle. Source: Heibonsha World Encyclopedia, 2nd Edition Information |
X線が10~3000Åくらいの大きさの微粒子を通過するとき,入射X線ときわめて小さい角度(通常1度以下)範囲に散漫な回折像や,ときには明らかな回折環を生じる。この現象をX線小角散乱または単に小角散乱という。また普通の結晶でも,長い周期をもつ物質のブラッグ反射はこの角度範囲にあらわれる。小角散乱による回折像を調べることによって,結晶のもつ非常に長い周期性の測定ができたり,微粒子の大きさ,形状,集合状態についての知識が得られる。
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