… N is called the normalization constant because it is determined to satisfy the normalization condition. ζ is called the orbital exponent, and is set to ζ = ( Z - 0.3)/ a ( Z is the atomic number). 0.3 represents the effect of the negative charges of the other electrons canceling out the electric field created by the positive charge of the nucleus, and is called the shielding constant. … *Some of the terminology that mentions "orbital index" is listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
…Nは規格化の条件を満たすように定められるので,規格化の定数と呼ばれる。ζは軌道指数と呼ばれ,ζ=(Z-0.3)/aとされる(Zは原子番号)。0.3は他電子の負電荷が原子核の正電荷のつくる電場を打ち消す効果を表し,さえぎりの定数と呼ばれる。… ※「軌道指数」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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