...Later, this theory was extended to polyatomic molecules by John Clarke Slater (1900-76) and LC Pauling, so it is also called the HLSP method, an acronym of their names. In this theory, the valence electrons in a molecule are considered to be close to belonging to atomic orbitals specific to each atom, so this theory is also called the atomic orbital method, or AO method for short. In contrast, the molecular orbital method (MO method) starts from the idea that the valence electrons are separated from the individual atomic orbitals and belong to molecular orbitals that extend throughout the molecule. ... *Some of the terminology used in reference to the "AO Act" is listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
…その後この理論はスレーターJohn Clarke Slater(1900‐76)やL.C.ポーリングにより多原子分子にも拡張されたので,彼らの名前の頭文字をとってHLSP法とも呼ばれている。この理論では,分子内の価電子は個々の原子に固有な原子軌道に属している状態に近いものと考えられるので,この理論は原子軌道法atomic orbital method,略してAO法とも呼ばれている。これに対し,分子軌道法(MO法)では,価電子は個々の原子軌道から離れて,分子全体に広がる分子軌道に属していると考えることから出発している。… ※「AO 法」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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