...Many new types of organometallic compounds were also discovered. Among them, ferrocene, in which an iron atom is sandwiched between two cyclopentadienes, was first created by PL Pauson in 1951, and became the base compound for many similar compounds (generally called metallocenes) that were created later. LC Pauling had pointed out the theoretical possibility that some of the rare gases could form compounds (1933), and Neil Bartlett (1907- ) succeeded in synthesizing xenon hexafluoroplatinate (1962), opening up the world of rare gas compounds. ... *Some of the terminology explanations that mention "Pauson, PL" are listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
…新しい形の有機金属化合物も数多く見いだされた。そのなかでも二つのシクロペンタジエンが鉄原子を挟み込んだフェロセンは,51年ポーソンP.L.Pausonによって初めてつくられ,後につくられた数多くの類似化合物(一般にメタロセンという)の基本化合物となった。希ガスの一部が化合物をつくる理論的可能性がL.C.ポーリングによって指摘されていたが(1933),バートレットNeil Bartlett(1907‐ )がヘキサフルオロ白金酸キセノンの合成に成功(1962)して,希ガス化合物の世界を開いた。… ※「Pauson,P.L.」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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