Zinc hydroxide

Japanese: 水酸化亜鉛 - すいさんかあえん(英語表記)zinc hydroxide
Zinc hydroxide

Zinc hydroxide. Chemical formula: Zn(OH) 2 , formula weight: 99.4. When an alkali hydroxide is added to an aqueous solution of zinc salt, a white precipitate is obtained. When heated to 125°C, it becomes zinc oxide. As an amphoteric hydroxide, it dissolves in acid to become zinc salt, and in alkali to become zincate.

Zn(OH) 2 +H 2 SO 4 →ZnSO 4 +2H 2 O
Zn(OH) 2 +2NaOH→Na 2 [Zn(OH) 4 ]
The zincate ion is usually written as ZnO 2 2- , but it is actually [Zn(OH) 4 ] 2- or [Zn(OH) 4 (H 2 O) 2 ] 2- , etc. It dissolves in ammonia water to form the complex ion [Zn(NH 3 ) 4 ] 2+ .

[Nakahara Katsunori]

Source: Shogakukan Encyclopedia Nipponica About Encyclopedia Nipponica Information | Legend

Japanese:

亜鉛の水酸化物。化学式Zn(OH)2、式量99.4。亜鉛塩の水溶液に水酸化アルカリを加えると白色の沈殿として得られる。加熱すれば125℃で酸化亜鉛となる。両性水酸化物で酸に溶けて亜鉛塩、アルカリに溶けて亜鉛酸塩となる。

  Zn(OH)2+H2SO4→ZnSO4+2H2O
  Zn(OH)2+2NaOH→Na2[Zn(OH)4]
 亜鉛酸イオンは普通ZnO22-と書くが、実は[Zn(OH)4]2-または[Zn(OH)4(H2O)2]2-などである。アンモニア水に溶けて錯イオン[Zn(NH3)4]2+になる。

[中原勝儼]

出典 小学館 日本大百科全書(ニッポニカ)日本大百科全書(ニッポニカ)について 情報 | 凡例

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