Exchange interaction -

Japanese: 交換相互作用 - コウカンソウゴサヨウ
Exchange interaction -

This is a spin-related interaction that occurs when the orbits of two electrons overlap each other. If the spins of the two electrons are s 1 and s 2 , respectively, then

-2 J ( s 1 s 2 )
where J is called the exchange integral. The exchange interaction between two magnetic atoms (or ions) is expressed as follows, where the spins of the atoms (ions) are S 1 and S 2 , respectively:

-2 J ( S 1S 2 )
The value of J , of course, depends on the atom (ion) and can be positive or negative. The same type of exchange interaction also exists when a non-magnetic atom exists between two magnetic atoms (ions), and in this case it is called a superexchange interaction. In magnetic materials, these interactions result in ferromagnetism and antiferromagnetism.

Source: Morikita Publishing "Chemical Dictionary (2nd Edition)" Information about the Chemical Dictionary 2nd Edition

Japanese:

二つの電子の軌道が互いに重なり合うときに生じるスピンに関係した相互作用.この相互作用は2電子のスピンをそれぞれ s1s2 とするとき

-2 J(s1s2)
として与えられ,Jは交換積分といわれる.磁気的な2原子(あるいはイオン)間の交換相互作用は,原子(イオン)のスピンをそれぞれ S1S2 とすると

-2 J(S1S2)
である.Jの値はもちろん原子(イオン)によって異なり,正あるいは負になる.二つの磁気的原子(イオン)の間に非磁気的原子が存在するときも,同じ形の交換相互作用が存在し,このときは超交換相互作用という.磁性体ではこれらの相互作用により,強磁性や反強磁性が出現する.

出典 森北出版「化学辞典(第2版)」化学辞典 第2版について 情報

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