…Boltzmann discovered the quantity E = ∫……∫ f log f dxdydzdv x dv y dv z , whose minimum value is proportional to entropy, as an analytical proof of the second law, and proved that E (called the H function) decreases with time when a gas is surrounded by fixed walls. This is called Boltzmann's H theorem, and Boltzmann himself considered this to have proven the second law, which states that entropy increases. However, since E has a different sign from entropy, Barbary later changed the letter E to H. … *Some of the terminology explanations that mention the "H theorem" are listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
…ボルツマンは第2法則の解析的証明として,極小値がエントロピーに比例する量E=∫……∫flogfdxdydzdvxdvydvzを発見し,気体が固定壁に囲まれているときE(H関数と呼ばれる)は時間とともに減少することを証明した。これをボルツマンのH定理といい,これによりボルツマン自身はエントロピーは増大するという第2法則は証明されたと考えた。ただし,Eはエントロピーとは符号が異なるので,のち,バーバリが文字EをHに変えた。… ※「H 定理」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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