... On the other hand, in the conventional use of natural gas, hydrogen cyanide is produced by reacting methane with ammonia and air, i.e., 2CH 4 + 2NH 3 + 3O 2 - → 2HCN + 6H 2 O. This method is called the Andrussow process. The products of the chlorination reaction of methane include methyl chloride (CH 3 Cl), methylene chloride (CH 2 Cl 2 ) , chloroform (CHCl 3 ) , and carbon tetrachloride (CCl 4 ) , which are used as solvents, aerosol propellants, and synthetic intermediates. ... *Some of the terminology used in reference to the Andre Russeau Process is listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
… 一方,天然ガスの在来型の利用は,シアン化水素はメタンとアンモニアおよび空気を反応させてつくられる。すなわち, 2CH4+2NH3+3O2―→2HCN+6H2Oこの方法はアンドルッソー法と呼ばれる。 メタンの塩素化反応生成物には,塩化メチルCH3Cl,塩化メチレンCH2Cl2,クロロホルムCHCl3,四塩化炭素CCl4などがあり,溶剤,エーロゾル噴霧剤,合成中間体などとして用いられる。… ※「アンドルッソー法」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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