…However, when many atoms or molecules come together to form a crystal, the electrons become waves (Bloch waves) that move around the entire crystal without belonging to any particular atom or molecule, and the energy levels form a band-like structure. For example, when N atoms are far enough apart, the energy levels E n of the electrons of free atoms exist in a degenerate set of N , but when the distance between the atoms decreases and they come closer to each other, the degeneracy is removed due to the interaction between the atoms, and energy levels with slightly different values are continuously distributed around E n , forming a single energy band (energy band). A collection of such energy bands (Figure 1) constitutes the entire energy levels of the electrons in the crystal and forms a band structure. … *Some of the terminology that mentions "energy band" is listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
…しかし多数の原子や分子が集まって結晶をつくると,電子は特定の原子や分子に所属することなく結晶全体を動きまわる波(ブロッホ波)となり,そのエネルギー準位は帯(バンド)状の構造をつくる。例えば,N個の原子が互いに十分遠く離れている場合には,自由原子の電子のエネルギー準位EnがそれぞれN個ずつ縮退して存在するが,原子間隔が小さくなって互いに近づくと,原子間の相互作用によって縮退がとれて,少しずつ値の異なるエネルギー準位がEnのまわりに連続的に分布して,一つのエネルギー帯(エネルギーバンドenergy band)をつくる。このようなエネルギー帯の集合(図1)が,結晶中の電子のエネルギー準位の全体を構成しバンド構造をつくる。… ※「energy band」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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