There are compounds of tin and sulfur in which tin is divalent and tetravalent. [Tin(II) sulfide] Chemical formula: SnS. When hydrogen sulfide is passed through an aqueous solution of tin(II) salt, it is obtained as a brown-black precipitate. Tin(II) sulfide, obtained by heating metallic tin and sulfur, is a gray crystal. It belongs to the orthorhombic crystal system and has a density of 5.08g/cm3. Its melting point is 880°C and its boiling point is 1230°C. At high temperatures, it tends to disproportionate into tin and tin(IV) sulfide. It has a rock salt structure and is practically insoluble in water (solubility is about 1.36× 10−6 g/ 100gH2O at 18°C). Source: Heibonsha World Encyclopedia, 2nd Edition Information |
スズと硫黄の化合物で,スズが2価と4価の化合物がある。 [硫化スズ(II)] 化学式SnS。スズ(II)塩の水溶液に硫化水素を通じると茶黒色の沈殿として得られる。金属スズと硫黄を加熱して得られる硫化スズ(II)は灰色の結晶。斜方晶系に属し,密度は5.08g/cm3。融点880℃,沸点1230℃。高温ではスズと硫化スズ(IV)とに不均化する傾向がある。岩塩型構造で,水にはほとんど溶けない(溶解度は18℃で1.36×10-6g/100gH2O程度)。 出典 株式会社平凡社世界大百科事典 第2版について 情報 |
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