[ I ] This refers to the CH3- group. It is the simplest alkyl group and is sometimes abbreviated as Me-. [ II ] This refers to the methyl radical. It can be produced by the photolysis of acetone or the thermal decomposition of methane. A methyl radical forms a flat equilateral triangle, and its C-H bond is 0.108 nm long. It is highly reactive, and will abstract an H from compounds that contain H to form methane. Methyl radicals can also recombine with each other to form ethane. Source: Morikita Publishing "Chemical Dictionary (2nd Edition)" Information about the Chemical Dictionary 2nd Edition |
【Ⅰ】CH3-基をいう.もっとも簡単なアルキル基で,Me-と略されることもある.【Ⅱ】メチルラジカルをいう.アセトンの光分解やメタンの熱分解でつくることができる.メチルラジカルは正三角形の平面をなし,C-H結合の長さは0.108 nm である.非常に反応性が高く,Hを含む化合物からHを引き抜いてメタンになる.また,メチルラジカルどうしは再結合してエタンになる. 出典 森北出版「化学辞典(第2版)」化学辞典 第2版について 情報 |
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