Chemical formula: HF. At room temperature, it is a colorless, fuming liquid. The gas is colorless, and the solid is white. The density of the liquid is 1.0015 g/cm3 (0°C), and that of the solid is 1.658 g/cm3 (-87.2°C). Its melting point is -83.0°C, and its boiling point is 19.5°C. Due to the strong hydrogen bonds between molecules, its boiling point is unusually high, despite its low molecular weight. As a result, its apparent molecular weight in the gas form is much greater than 20, and is not constant depending on temperature or pressure. At 90°C, it has a value equivalent to HF, and at 32°C, it has a value intermediate between H 2 F 2 and H 3 F 3 . Source: Heibonsha World Encyclopedia, 2nd Edition Information |
化学式HF。常温では無色,発煙性の液体。気体は無色,固体は白色。密度は液体で1.0015g/cm3(0℃),固体で1.658g/cm3(-87.2℃)。融点は-83.0℃,沸点は19.5℃。分子間の強い水素結合のため,低分子量の物質にもかかわらず,沸点が異常に高い。そのため気体における見かけの分子量は20よりはるかに大きく,温度,圧力に依存して一定値を与えない。90℃ではHFに相当する値を,また32℃ではH2F2とH3F3との中間の値をとる。
出典 株式会社平凡社世界大百科事典 第2版について 情報 |
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