LiOH (23.95). The monohydrate is obtained from aqueous solution by reaction of lithium carbonate with calcium hydroxide. The anhydrous form is obtained by dehydration with diphosphorus pentoxide in a vacuum. The anhydrous form is a white solid. Density 1.46 g cm -3 . Melting point 450 °C. Decomposes at 924 °C to Li 2 O. Absorbs carbon dioxide. It is hygroscopic, soluble in water, slightly soluble in ethanol. Its aqueous solution is strongly alkaline. The monohydrate is a colorless monoclinic crystal. Density 1.51 g cm -3 . Soluble in water, insoluble in ether. Used in the manufacture of lithium compounds, photographic developers, batteries, carbon dioxide absorbents, greases, ceramics, etc. [CAS 1310-65-2: LiOH][CAS 1310-66-3: LiOH・H 2 O] Source: Morikita Publishing "Chemical Dictionary (2nd Edition)" Information about the Chemical Dictionary 2nd Edition |
LiOH(23.95).炭酸リチウムと水酸化カルシウムとの反応により,水溶液から一水和物が得られる.真空中で五酸化二リンを用いて脱水して無水物が得られる.無水物は白色の固体.密度1.46 g cm-3.融点450 ℃.924 ℃ で分解してLi2Oとなる.二酸化炭素を吸収する.吸湿性で水に可溶,エタノールに微溶.水溶液は強塩基性を示す.一水和物は無色の単斜晶系結晶.密度1.51 g cm-3.水に可溶,エーテルに不溶.リチウム化合物の製造,写真現像液,電池,二酸化炭素吸収剤,グリース,陶磁器などに用いられる.[CAS 1310-65-2:LiOH][CAS 1310-66-3:LiOH・H2O] 出典 森北出版「化学辞典(第2版)」化学辞典 第2版について 情報 |
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