Zr(SiO 4 ). Also called hyacinthite. Nesosilicate. Found as an accessory mineral in plutonic and metamorphic rocks. Tetragonal crystal system, space group I 4/ amd . Lattice constants a 0 = 0.660, c 0 = 0.598 nm. {110} incomplete cleavage. Hardness 7.5. Density 4.6-4.7 g cm -3 . Reddish brown to yellow. Becomes colorless and transparent when ignited in a reducing environment. Positive uniaxiality. ω 1.923-1.960, ε 1.968-2.015, ε-ω 0.042-0.065. When part of the Zr is replaced by U or Th, it is often metamictized. Natural zircon always contains a certain amount of Hf, and some zircons with Hf/Zr ratios of 0.6 have been found. It can be artificially obtained by hydrothermal synthesis of ZrO2 and SiO2 at temperatures ranging from 150 to 700°C. Source: Morikita Publishing "Chemical Dictionary (2nd Edition)" Information about the Chemical Dictionary 2nd Edition |
Zr(SiO4).ヒヤシンス鉱ともいう.ネソケイ酸塩.深成岩,変成岩中に副成分鉱物として含まれる.正方晶系,空間群 I4/amd.格子定数 a0 = 0.660,c0 = 0.598 nm.へき開{110}不完全.硬度7.5.密度4.6~4.7 g cm-3.赤褐色~黄色.還元環境で強熱すると無色透明になる.一軸性正.ω 1.923~1.960,ε 1.968~2.015,ε-ω 0.042~0.065.Zrの一部がU,Thで置換されているとメタミクト化している場合が多い.また,天然のジルコンはつねにHfをある程度含んでおり,Hf/Zrが0.6のものも見いだされている.人工的にはZrO2とSiO2を150~700 ℃ の範囲で水熱合成して得られる. 出典 森北出版「化学辞典(第2版)」化学辞典 第2版について 情報 |
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