Usually, this refers to lead(II) chromate. It occurs naturally as chromite. It is obtained as a precipitate when water-soluble chromate or dichromate is added to an aqueous solution of lead(II) acetate or lead(II) nitrate. It is a yellow crystal. Those containing small amounts of impurities are blackish or reddish. It is practically insoluble in water, but dissolves in alkali to form zincate M I 2 PbO 2. It also dissolves in acid, and turns black with hydrogen sulfide, but is stable in light and air. It is the main component of yellow lead (chrome yellow), a yellow pigment. It is also mixed with copper oxide to remove sulfur oxides from combustion gases during elemental analysis of carbon and hydrogen. [Kenichi Morinaga and Katsunori Nakahara] [References] | [Supplementary information] |Source: Shogakukan Encyclopedia Nipponica About Encyclopedia Nipponica Information | Legend |
普通、クロム酸鉛(Ⅱ)をいう。天然に紅鉛鉱として産出する。酢酸鉛(Ⅱ)や硝酸鉛(Ⅱ)の水溶液に水溶性のクロム酸塩または二クロム酸塩を加えると沈殿として得られる。黄色結晶。少量の不純物を含むものは黒みや赤みを帯びている。水にはほとんど溶けないが、アルカリには亜鉛酸塩MI2PbO2をつくって溶ける。酸にも溶け、硫化水素で黒色となるが、光、空気に対しては安定である。黄色顔料として知られる黄鉛(クロムエロー)の主成分である。また、炭素・水素の元素分析に際し、燃焼ガス中から硫黄(いおう)の酸化物を除くため酸化銅と混ぜて用いられる。 [守永健一・中原勝儼] [参照項目] | [補完資料] |出典 小学館 日本大百科全書(ニッポニカ)日本大百科全書(ニッポニカ)について 情報 | 凡例 |
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