Endothermic reaction - Endothermic reaction

Japanese: 吸熱反応 - きゅうねつはんのう(英語表記)endothermic reaction
Endothermic reaction - Endothermic reaction

A chemical reaction is a reaction that absorbs heat as it progresses. In contrast, a reaction that generates heat is called an exothermic reaction. When a chemical reaction occurs at a constant temperature from an original system to a product system, a reaction that must absorb heat from the outside to complete the reaction is an endothermic reaction. If the energy of a system is expressed in enthalpy (heat content), the enthalpy H of the system increases by the amount of heat absorption ( ΔH >0).

2Cl 2 +O 2 ―→2Cl 2 O-126.4kJ
or 2Cl2 + O2 - → 2Cl2O ΔH = 126.4 kJ
Examples include. In general, endothermic reactions are difficult to occur naturally, so it is necessary to raise the temperature to proceed with the reaction. When this endothermic reaction is a reversible reaction and it reaches equilibrium, the equilibrium constant increases with increasing temperature.

[Toda Genjiro]

Source: Shogakukan Encyclopedia Nipponica About Encyclopedia Nipponica Information | Legend

Japanese:

化学反応が進行するにつれて、熱を吸収する反応をいう。これに対し、熱を発生する反応を発熱反応という。化学反応が一定の温度の下で原系から生成系へとおこる場合、反応を完結させるために外部から熱量を吸収しなければならない反応が吸熱反応である。系のエネルギーをエンタルピー(熱含量)で表せば、この吸熱部分だけ系のエンタルピーHは増加する(ΔH>0)。

  2Cl2+O2―→2Cl2O-126.4kJ
または
  2Cl2+O2―→2Cl2O ΔH=126.4kJ
などがその例である。一般に吸熱反応は自然にはおこりにくいので、温度を上げて反応を進める必要がある。この吸熱反応が可逆反応で、それが平衡に達したとき、平衡定数は温度が上昇するとともに増加する。

[戸田源治郎]

出典 小学館 日本大百科全書(ニッポニカ)日本大百科全書(ニッポニカ)について 情報 | 凡例

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