Bridge group - Kakyodan
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…An example of a hexadentate ligand is EDTA, which is coordinated with two N and four O. In contrast to a polydentate ligand, a ligand in which one ligand is coordinated with two central metal ions is called a bridging group or bridging ligand. Examples include the OH in [(H 3 N) 5 Cr-OH-Cr(NH 3 ) 5 ]Cl 5 and the CH 3 COO- in the following [Cu 2 (CH 3 COO) 4 (H 2 O) 2 ]. … *Some of the terminology that refers to "crosslinking groups" is listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
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…六座配位子にはEDTAがあり，二つのN，四つのOで配位している。多座配位子に対し，一つの配位子が二つの中心金属イオンに配位している配位子は架橋団あるいは橋架け配位子という。[(H3N)5Cr－OH－Cr(NH3)5]Cl5の中のOHや，次に示す[Cu2(CH3COO)4(H2O)2]のCH3COO－がこれに当たる。… ※「架橋団」について言及している用語解説の一部を掲載しています。 出典｜株式会社平凡社世界大百科事典 第２版について | 情報 |
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