f block elements

Japanese: f ブロック元素 - えふぶろっくげんそ
f block elements

...The electron arrangement of the outermost part of the atom is not precisely known, but it is generally assumed to be 5f n 6s 2 6p 6 7s 2 or 5f n 6s 2 6p 6 6d 1 7s 2 , and the way in which the number of 5f electrons increases from 0 to 14 is very similar to that of the lanthanides, whose 4f electrons increase in the same way. For this reason, they are placed below the lanthanides in the periodic table, and together with them are also called "inner transition elements" or "f-block elements". However, chemically they exhibit more complex behavior, forming compounds with various oxidation numbers as shown in the table, but elements below curium Cm are stable in the trivalent state, and are more similar to the lanthanides. ...

*Some of the terminology that refers to the "f block elements" is listed below.

Source | Heibonsha World Encyclopedia 2nd Edition | Information

Japanese:

…原子の最外部の電子配列は正確に知られていないものが多いが,一般に5fn6s26p67s2または5fn6s26p66d17s2と推定され,5f電子の数が0から14まで増加していく様子は,4f電子が同様に増加するランタノイドとよく似ている。このため,周期表ではランタノイドの下に置かれ,これと一括して〈内部遷移元素〉〈fブロック元素〉などとも呼ばれる。しかし化学的にはより複雑な挙動を示し,表に示すような種々の酸化数の化合物をつくるが,キュリウムCm以下の元素は3価の状態が安定となり,ランタノイドとの類似が著しくなる。…

※「f ブロック元素」について言及している用語解説の一部を掲載しています。

出典|株式会社平凡社世界大百科事典 第2版について | 情報

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