Chemical formula: NH 4 I. Colorless crystals. At room temperature, it has a cubic crystal system (α-form) with a sodium chloride structure and a lattice constant of 7.244 Å. Specific gravity: 2.511. At temperatures below -17.6°C, it has a cesium chloride structure (β-form) with a lattice constant of 4.37 Å. At temperatures below -41.6°C, it becomes the γ-form. In the γ-form, the tetrahedral NH 4 + is tetrahedral in symmetry due to hydrogen bonds between N-H...I, but in the β-form, it is cubic in symmetry because it does not face in a fixed direction. When heated, it sublimes at 551°C. It is deliquescent and photosensitive. Source: Heibonsha World Encyclopedia, 2nd Edition Information |
化学式NH4I。無色の結晶。室温では立方晶系(α形)で,塩化ナトリウム型構造,格子定数7.244Å。比重2.511。-17.6℃以下では塩化セシウム型構造(β形),格子定数4.37Å。-41.6℃以下ではγ形となる。γ形では正四面体のNH4+がN-H…Iの水素結合によって四面体対称となっているのに,β形では一定の方向を向いていないため立方体対称となっている。熱すると551℃で昇華する。潮解性であり,また感光性がある。
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