Chemical formula: B3N3H6 . It is a colorless liquid with an aromatic odor, obtained by reacting boron trichloride with ammonium chloride to produce trichloroborazole B3N3H3Cl3 , which is then reduced with lithium tetrahydroborate LiBH4 . Its melting point is -58°C, boiling point is 53°C, and specific gravity is 0.81 (liquid, near the boiling point), 1.00 (solid, near the melting point). Its molecular structure is a planar regular hexagon similar to that of benzene, and the B-N bond has pi-bonding properties. It is also known as inorganic benzene because it behaves similarly to benzene, with hydrogen atoms being replaced by alkyl and allyl groups. Source: Heibonsha World Encyclopedia, 2nd Edition Information |
化学式B3N3H6。三塩化ホウ素と塩化アンモニウムとを反応させてトリクロロボラゾールB3N3H3Cl3をつくり,これをテトラヒドロホウ酸リチウムLiBH4で還元して得られる,無色の芳香族臭ある液体。融点-58℃,沸点53℃,比重0.81(液体,沸点近くで),1.00(固体,融点近くで)。分子構造はベンゼンと似た平面正六角形で,B-N結合はπ結合性をもつ。また水素原子はアルキル基,アリル基で置換されるなどベンゼン類似の挙動を示すため,無機ベンゼンの異名がある。
出典 株式会社平凡社世界大百科事典 第2版について 情報 |
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