…The above relationship holds true well for weak electrolytes such as acetic acid, but for strong electrolytes such as sodium chloride, the value of the ionization constant calculated by the above formula is not constant, and there is a significant deviation from the law of mass action. In other words, the properties of strong electrolyte solutions cannot be explained by the Arrhenius theory of ionization equilibrium (this is called the anomaly of strong electrolytes). [Tamamushi Reita]. … *Some of the terminology that refers to "strong electrolyte abnormalities" is listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
…酢酸のような弱電解質の場合には以上の関係がよく成立するが,塩化ナトリウムのような強電解質では,上式による電離定数の値が一定にならず,質量作用の法則からのずれが著しい。すなわち,強電解質溶液の性質は,アレニウスの電離平衡の理論では説明することができない(これを強電解質の異常という)。【玉虫 伶太】。… ※「強電解質の異常」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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