…[Al(H 2 O) 6 ] 3+ ⇄[Al(H 2 O) 5 (OH)] 2+ +H + The resulting complex with hydroxo ligands can polymerize, for example, as shown in the following formula, to form a dinuclear complex with a hydroxo bridge (formerly called an ol bridge) via the bridging ligand OH- . This reaction is called olation. The formation of gelatinous hydroxides of Al III , Fe III , Cr III , etc. can be explained as a further progression of this olation. … *Some of the terminology that mentions "olation" is listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
… [Al(H2O)6]3+⇄[Al(H2O)5(OH)]2++H+ 生じたヒドロキソ配位子をもつ錯体は,たとえば次式に示すように二つが重合して,OH-の橋架け配位子によるヒドロキソ橋(古くはオール橋といった)をもつ複核錯体をつくる。この反応をオール化olationという。AlIII,FeIII,CrIIIなどのゼラチン状水酸化物の生成は,このオール化がさらに進行したものとして説明される。… ※「olation」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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