In the narrow sense, it refers to potassium alum, KAl(SO 4 ) 2 ·12H 2 O, and simply speaking alum refers to this. In general, it refers to a double salt in which Na(+/), NH 4 (+/), Rb(+/), Cs(+/), Tl(+/), etc. are combined in place of K (+/), and it is called sodium alum, ammonium alum, etc. depending on the type of substituted cation. All are colorless octahedral crystals with properties similar to potassium alum. In a broader sense, it also includes those in which other trivalent metals such as Ga 3 (+/), In 3 (+/), Ti 3 (+/), V 3 (+/), Cr 3 (+/), Mn 3 (+/), Fe 3 (+/), Co 3 (+/), etc. are combined in place of Al 3 (+/) (chrome alum, iron alum). Some of these are colored, but all are regular octahedral crystals that dissolve in water. Also, those that have selenate groups instead of sulfate groups, such as TlCr(SeO 4 ) 2 ·12H 2 O, are called selenium alum. → Related topicsGargle|Hemostatic|Cast alum Source : Heibonsha Encyclopedia About MyPedia Information |
狭義にはカリミョウバンKAl(SO4)2・12H2Oをいい,単にミョウバンといえばこれをさす。一般にはK(+/)の代りにNa(+/),NH4(+/),Rb(+/),Cs(+/),Tl(+/)などが結合した複塩をいい,代りになった陽イオンの種類によりそれぞれナトリウムミョウバン,アンモニウムミョウバンなどと呼ぶ。いずれも正八面体の無色の結晶で,カリミョウバンに似た性質をもつ。さらに広義にはAl3(+/)の代りに他の3価の金属のGa3(+/),In3(+/),Ti3(+/),V3(+/),Cr3(+/),Mn3(+/),Fe3(+/),Co3(+/)などが入ったものも含めていう(クロムミョウバン,鉄ミョウバン)。これらには有色のものもあるが,いずれも正八面体の水に溶ける結晶。またTlCr(SeO4)2・12H2Oのように硫酸基の代りにセレン酸基の入ったものをセレンミョウバンという。 →関連項目うがい薬|止血薬|焼ミョウバン(明礬) 出典 株式会社平凡社百科事典マイペディアについて 情報 |
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