An acid thought to exist when diarsenic trioxide As 2 O 3 is dissolved in water. It is represented by the chemical formula H 3 AsO 3 , HAsO 2 , etc., but is not obtained in a free state. Although it is a weak acid, it is amphoteric and also acts as a base. Acid dissociation constant K a = 6 × 10 -6 (HAsO 2 ⇄H + +AsO 2 - ), base dissociation constant K b = 10 -14 (AsO(OH)⇄AsO + +OH - ). It is stable in neutral and slightly acidic aqueous solutions, but in alkaline aqueous solutions it is easily oxidized by air to become arsenic acid. Source: Heibonsha World Encyclopedia, 2nd Edition Information |
三酸化二ヒ素As2O3を水に溶かしたときに存在すると考えられる酸。化学式H3AsO3,HAsO2などであらわされるが,遊離状態では得られていない。弱酸であるが両性を示し,塩基としても働く。酸解離定数Ka=6×10-6(HAsO2⇄H++AsO2-),塩基解離定数Kb=10-14(AsO(OH)⇄AsO++OH-)。中性および微酸性水溶液は安定であるが,アルカリ性水溶液では空気により酸化されてヒ酸となりやすい。
出典 株式会社平凡社世界大百科事典 第2版について 情報 |
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