A high-pressure phase of SiO 2. It was discovered in the meteorite crater in Arizona where stishovite was discovered, Arabia, southern Germany, and other places. It was later synthesized by L. Coes Jr. (1953) at 500-800 °C and 3.5 GPa. It is a transformation of quartz caused by the shock pressure of a meteorite fall. Low-pressure SiO 2 becomes coesite at 500 °C and 2.5 GPa, and at 1500 °C and 3.5 GPa. Monoclinic system, space group C 2/ c , lattice constants a 0 = 0.714, b 0 = 1.237, c 0 = 0.714 nm. β = 120°. Density 2.915 g cm -3 (measured), 2.919 g cm -3 (calculated). Source: Morikita Publishing "Chemical Dictionary (2nd Edition)" Information about the Chemical Dictionary 2nd Edition |
SiO2の高圧相.スチショバイトの発見されたアリゾナのいん石孔,アラビア,南ドイツなどで発見された.その後,L.Coes Jr.(1953年)が500~800 ℃,3.5 GPa 下で合成した.いん石落下による衝撃圧によって石英が転移したもの.低圧型SiO2は500 ℃,2.5 GPa で,また1500 ℃,3.5 GPa でコーサイトになる.単斜晶系,空間群 C 2/c,格子定数 a0 = 0.714,b0 = 1.237,c0 = 0.714 nm.β = 120°.密度2.915 g cm-3(実測),2.919 g cm-3(計算). 出典 森北出版「化学辞典(第2版)」化学辞典 第2版について 情報 |
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