...The main step in a reaction is when an electrophilic reagent, such as a cation (hydrogen ion H + or nitronium ion NO2 + ) or a Lewis acid (aluminum chloride AlCl3 or boron fluoride BF3 ), attacks the unsaturated bond or unshared electron pair of the substrate. Electrophilic reactions are broadly divided into (1) electrophilic substitution reactions, in which (part of) the reagent replaces part of the substrate, and (2) electrophilic addition reactions, in which the reagent is added to the multiple bond of the substrate. Electrophilic substitution reactions are likely to occur in aromatic compounds. ... From [Organic Chemical Reactions] ...These are known as the substituent effects. *Some of the terminology that refers to "electrophilic addition reaction" is listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
…一般に陽イオン(水素イオンH+やニトロニウムイオンNO2+など)やルイス酸(塩化アルミニウムAlCl3やフッ化ホウ素BF3など)の求電子試薬が基質の不飽和結合や非共有電子対を攻撃する段階が反応の中心となる。 求電子反応は,(1)試薬(の一部)が基質の一部と置換する求電子置換反応と,(2)試薬が基質の多重結合に付加する求電子付加反応に大別される。求電子置換反応は芳香族化合物に起こりやすい。… 【有機化学反応】より…これらはいわゆる置換基効果substituent effectとして知られている。 ※「求電子付加反応」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
>>: Electrophilic substitution reaction
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