...In other words, the above reaction between the solid and gas phases can be considered a neutralization reaction, and although it is said that CaO is a basic oxide and CO2 is an acidic oxide, we should consider them as a base and an acid. In other words, H. Lux announced in 1939 and H. Flood announced in 1947 the concept of considering the oxide ion O2- donor as a base and the acceptor as an acid in dry reactions. This can be considered to be the exact opposite of the H + -centered view of Brensted-Lowry, H2O⇄2H + + O2- . ... *Some of the terminology that mentions "Flood, H." is listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
…すなわち固相と気相の上記の反応でも中和反応と考えてよいし,CaOは塩基性酸化物,CO2は酸性酸化物であるといわれるが,これらを塩基と酸と考えようというのである。すなわちルクスH.Luxは1939年,フラッドH.Floodは47年,乾式反応での酸・塩基として,酸化物イオンO2-供与体を塩基,受容体を酸と考える概念を発表している。ブレーンステズ=ローリーのH+を中心とした見方を,H2O⇄2H++O2-からちょうど逆の考え方としているものと考えることができる。… ※「Flood,H.」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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