… It is expressed as p – c + f = 2. It was derived by the American J.W. Gibbs in the late 19th century and is also called the Gibbs phase rule. This equation is derived from the requirement that in order for equilibrium to exist between phases, the chemical potentials of each component must be equal in each coexisting phase. … *Some of the terminology explanations that refer to "Gibbs' Phase Rule" are listed below. Source | Heibonsha World Encyclopedia 2nd Edition | Information |
…p-c+f=2で表される。19世紀後半にアメリカのJ.W.ギブズによって導かれたもので,ギブズの相律とも呼ばれる。この関係式は,相の間に平衡が成り立つためには各成分の化学ポテンシャルが共存するそれぞれの相で互いに等しくならなければならないという要請から導かれる。… ※「ギブズの相律」について言及している用語解説の一部を掲載しています。 出典|株式会社平凡社世界大百科事典 第2版について | 情報 |
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